Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: their use for hydrogenolysis-free hydrogenation of olefins
- 16 November 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry
- Vol. 28 (12), 1550-1553
- https://doi.org/10.1039/b409604e
Abstract
Carbon-carbon double bonds have been selectively hydrogenated at room temperature in the presence of benzyloxy groups using an atmospheric pressure of hydrogen, toluene or [bmim]PF6 as the solvent and palladium nanoparticles stabilized with tetrabutylammonium bromide. The system [bmim]PF6/palladium nanoparticles can be recycled without noticeable decrease of activity.Keywords
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