Poly[bis(phenethylammonium) [dibromidoplumbate(II)]-di-μ-bromido]]
Open Access
- 7 October 2009
- journal article
- research article
- Published by International Union of Crystallography (IUCr) in Acta Crystallographica Section E: Crystallographic Communications
- Vol. 65 (11), m1323-m1324
- https://doi.org/10.1107/S160053680903712X
Abstract
Crystals of the title compound, {(C6H5C2H4NH3)(2)[PbBr4]}(n), were grown at room temperature from a solution in N,N-dimethylformamide (DMF) using nitromethane as the poor solvent. This perovskite-type organic-inorganic hybrid compound consists of well ordered sheets of corner-sharing disordered PbBr6 octahedra separated by bilayers of phenethylammonium cations. The octahedra are rotated and tilted due to N-H center dot center dot center dot Br hydrogen bonds with the ammonium groups, generating a superstructure in the unit cell similar to that of the tetrachloridoplumbate (C6H5C2H4NH3)(2)[PbCl4].Keywords
This publication has 6 references indexed in Scilit:
- Subnanosecond time-resolved x-ray measurements using an organic-inorganic perovskite scintillatorApplied Physics Letters, 2008
- A short history of SHELXActa Crystallographica Section A Foundations of Crystallography, 2007
- Structure of the organic–inorganic hybrid (C6H5C2H4NH3)2ZnBr4Current Applied Physics, 2006
- Layered organic–inorganic perovskite-type hybrid materials fabricated by spray pyrolysis routeJournal of Crystal Growth, 2005
- Optical properties of self-assembled nano-hybrid materialsSurface and Coatings Technology, 2005
- Bis[(S)-β-phenethylammonium] tribromoplumbate(II)Acta Crystallographica Section E Structure Reports Online, 2003