Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks
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- 12 March 2012
- journal article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 41 (18), 5458-5460
- https://doi.org/10.1039/c2dt30174a
Abstract
Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.Keywords
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