Self-assembled V2O5 nanosheets/reduced graphene oxide hierarchical nanocomposite as a high-performance cathode material for lithium ion batteries
- 2 July 2013
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry A
- Vol. 1 (36), 10814-10820
- https://doi.org/10.1039/c3ta12066j
Abstract
A simple solvothermal method was used to prepare self-assembled V2O5 nanosheets/reduced graphene oxide (RGO) hierarchical nanocomposite. In this nanocomposite, the V2O5 nanosheets assembling on the RGO constitute a 3-D hierarchical nanostructure with high specific surface area and good electronic/ionic conducting path. When used as the cathode materials, the V2O5 nanosheets/RGO nanocomposites exhibit highly reversible capacity and good rate capability relative to the bulk material. The V2O5 nanosheets/RGO nanocomposite anode was able to charge/discharge at high current densities of 3000 mA g−1 (10 C), 6000 mA g−1 (20 C) and 15 A g−1 (50 C), with discharge capacities of approximately 138, 112 and 76 mA h g−1, respectively. Meanwhile, a discharge capacity of 102 mA h g−1 can be delivered after 160 cycles at 2 C, showing a good cycling stability. The improved performance could be attributed to the enhanced electron transport and Li+ diffusion that results from the hierarchical nanostructure of V2O5 nanosheets/RGO nanocomposites.Keywords
This publication has 42 references indexed in Scilit:
- Electrospun V2O5 Nanostructures with Controllable Morphology as High‐Performance Cathode Materials for Lithium‐Ion BatteriesChemistry – A European Journal, 2012
- Core–Shell Structure of Polypyrrole Grown on V2O5 Nanoribbon as High Performance Anode Material for SupercapacitorsAdvanced Energy Materials, 2012
- V2O5Hollow Nanospheres: A Lithium Intercalation Host with Good Rate Capability and Capacity RetentionJournal of the Electrochemical Society, 2012
- A Nanonet-Enabled Li Ion Battery Cathode Material with High Power Rate, High Capacity, and Long Cycle LifetimeACS Nano, 2011
- Synthesis and characterization of self-assembled nanofiber-bundles of V2O5: their electrochemical and field emission propertiesNanoscale, 2011
- Carbon-Coated V2O5 Nanocrystals as High Performance Cathode Material for Lithium Ion BatteriesChemistry of Materials, 2011
- Facile synthesized nanorod structured vanadium pentoxide for high-rate lithium batteriesJournal of Materials Chemistry, 2010
- Lithium batteries: Status, prospects and futureJournal of Power Sources, 2010
- Developments in Nanostructured Cathode Materials for High‐Performance Lithium‐Ion BatteriesAdvanced Materials, 2008
- Nanostructured Vanadium Oxide Electrodes for Enhanced Lithium‐Ion IntercalationAdvanced Functional Materials, 2006