Halogen Bonding and π···π Stacking Control Reactivity in the Solid State
Top Cited Papers
- 23 March 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (14), 4500-4501
- https://doi.org/10.1021/ja039884n
Abstract
The halogen bonding and the π···π stacking interactions induce the noncovalent self-assembly of modules into photoreactive supramolecular architecture. The π···π interaction pre-organizes the template, and the halogen bonding aligns the olefins to conform to the topochemical principle for photoreaction. The UV irradiation of the crystal resulted in a cyclization product with quantitative yield and stereospecificity.This publication has 18 references indexed in Scilit:
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