Yttrium alkyl complexes with a sterically demanding benzamidinate ligand: synthesis, structure and catalytic ethene polymerisationElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b2/b208502j/

Abstract

The benzamidinate yttrium dialkyl complexes [PhC(NAr)₂]Y(CH₂SiMe₃)₂(THF)_n (Ar = 2,6-diisopropylphenyl; n = 1, 2) were prepared; when activated with [PhNMe₂H][B(C₆F₅)₄], the species with n = 1 polymerises ethene to polyethene with a narrow polydispersity.