Constructing a Strongly Absorbing Low‐Bandgap Polymer Acceptor for High‐Performance All‐Polymer Solar Cells

Abstract

All-polymer solar cells (all-PSCs) offer unique morphology stability for the application as flexible devices, but the lack of high-performance polymer acceptors limits their power conversion efficiency (PCE) to a value lower than those of the PSCs based on fullerene derivative or organic small molecule acceptors. We herein demonstrate a strategy to synthesize a high-performance polymer acceptor PZ1 by embedding an acceptor–donor–acceptor building block into the polymer main chain. PZ1 possesses broad absorption with a low band gap of 1.55 eV and high absorption coefficient (1.3×10⁵ cm⁻¹). The all-PSCs with the wide-band-gap polymer PBDB-T as donor and PZ1 as acceptor showed a record-high PCE of 9.19 % for the all-PSCs. The success of our polymerization strategy can provide a new way to develop efficient polymer acceptors for all-PSCs.