Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [γ-SiW10O36]8−: A Totally Inorganic Oxygen-Evolving Catalyst
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- 18 March 2008
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 130 (15), 5006-5007
- https://doi.org/10.1021/ja077837f
Abstract
Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, γ-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h−1Keywords
This publication has 27 references indexed in Scilit:
- Multiple Reversible Protonation of Polyoxoanion Surfaces: Direct Observation of Dynamic Structural Effects from Proton TransferAngewandte Chemie, 2007
- Asymmetric Tetraprotonation of γ‐[(SiO4)W10O32]8− Triggers a Catalytic Epoxidation Reaction: Perspectives in the Assignment of the Active CatalystAngewandte Chemie, 2007
- Dilacunary Decatungstates Functionalized by Organometallic Ruthenium(II), [{Ru(C6H6)(H2O)}{Ru(C6H6)}(γ-XW10O36)]4- (X = Si, Ge)Inorganic Chemistry, 2006
- A New Family of Ru Complexes for Water OxidationJournal of the American Chemical Society, 2005
- Synthesis, Characterization, and Photochemical Behavior of {Ru(arene)}2+Derivatives of α-[PW11O39]7-: An Organometallic Way to Ruthenium-Substituted HeteropolytungstatesInorganic Chemistry, 2005
- A Diruthenium-Substituted Polyoxometalate as an Electrocatalyst for Oxygen GenerationJournal of the American Chemical Society, 2004
- A New Ru Complex Capable of Catalytically Oxidizing Water to Molecular DioxygenJournal of the American Chemical Society, 2004
- Sliding Helix and Change of Coordination Geometry in a Model Di‐MnII ProteinAngewandte Chemie, 2003
- Structure of Tetrameric Aqua Ruthenium(IV): an Investigation by Ruthenium K Edge EXAFSInorganic Chemistry, 1998
- The tetranuclear ruthenium(IV) aqua ion: evidence in support of its formulation as Hn[Ru4O6(OH2)12](4+n)+ (n = 0-4)Inorganic Chemistry, 1991