Chemical functionalization of graphene
- 27 July 2009
- journal article
- Published by IOP Publishing in Journal of Physics: Condensed Matter
- Vol. 21 (34), 344205
- https://doi.org/10.1088/0953-8984/21/34/344205
Abstract
Experimental and theoretical results on chemical functionalization of graphene are reviewed. Using hydrogenated graphene as a model system, general principles of the chemical functionalization are formulated and discussed. It is shown that, as a rule, 100% coverage of graphene by complex functional groups (in contrast with hydrogen and fluorine) is unreachable. A possible destruction of graphene nanoribbons by fluorine is considered. The functionalization of infinite graphene and graphene nanoribbons by oxygen and by hydrofluoric acid is simulated step by step.Keywords
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