Tunneling Through High Periodic Barriers. I
- 1 November 1956
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 25 (5), 896-903
- https://doi.org/10.1063/1.1743139
Abstract
Analytic expressions for tunneling frequencies through high periodic barriers are derived. The expression for wells of threefold symmetry is applied to the analysis of microwave data on CH3SiF3, CH3SiH3, and CH3SiD3 and values of the barrier heights of 1 kcal, 1.5 kcal, and 1.5 kcal per mole, respectively, are obtained, which are in reasonable agreement with previously obtained values.This publication has 8 references indexed in Scilit:
- Theory of the Interaction of Hindered Internal Rotation with Over-All Rotations. I. Symmetric Rotors: Methyl SilaneThe Journal of Chemical Physics, 1954
- The Molecular Structure of Methyl AlcoholPhysical Review B, 1951
- The Microwave Spectra and Molecular Structures of Trifluorosilane DerivativesThe Journal of Chemical Physics, 1951
- An Electrostatic Theory of the Potential Barriers Hindering Rotation around Single BondsThe Journal of Chemical Physics, 1949
- Hindered Rotation in Methyl AlcoholPhysical Review B, 1940
- The Two-Minima Problem and the Ammonia MoleculePhysical Review B, 1932
- XVII.—On the Asymptotic Expansion of the Characteristic Numbers of the Mathieu EquationProceedings of the Royal Society of Edinburgh, 1930
- XXVIII.—Researches into the Characteristic Numbers of the Mathieu Equation—(Second Paper)Proceedings of the Royal Society of Edinburgh, 1927