Synthesis and Properties of Homologous Series of Polyallylcarbosilane Dendrimers with Dense Macromolecular Structure
- 30 March 2009
- journal article
- research article
- Published by Wiley in Macromolecular Symposia
- Vol. 278 (1), 14-23
- https://doi.org/10.1002/masy.200950403
Abstract
Synthesis of the six generations of polyallylcarbosilane dendrimers with tetrafunctional branching center and tetrafunctional base reagent is reported. Obtained dendrimers are compared to carbosilane dendrimers with less dense molecular structure synthesized before. Densification of the dendrimer structure alters some basic dendrimer properties as well as their dependence on generation.Keywords
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