A cobalt complex redox shuttle for dye-sensitized solar cells with high open-circuit potentials

Abstract

Dye-sensitized solar cells are a promising alternative to traditional inorganic semiconductor-based solar cells. Here we report an open-circuit voltage of over 1,000 mV in mesoscopic dye-sensitized solar cells incorporating a molecularly engineered cobalt complex as redox mediator. Cobalt complexes have negligible absorption in the visible region of the solar spectrum, and their redox properties can be tuned in a controlled fashion by selecting suitable donor/acceptor substituents on the ligand. This approach offers an attractive alternate to the traditional I₃⁻/I⁻ redox shuttle used in dye-sensitized solar cells. A cobalt complex using tridendate ligands [Co(bpy-pz)₂]^3+/2+(PF₆)_3/2 as redox mediator in combination with a cyclopentadithiophene-bridged donor-acceptor dye (Y123), adsorbed on TiO₂, yielded a power conversion efficiency of over 10% at 100 mW cm⁻². This result indicates that the molecularly engineered cobalt redox shuttle is a legitimate alternative to the commonly used I₃⁻/I⁻ redox shuttle.