Molecular catalysis: enhanced rates of thiolysis with high structural and chiral recognition in complexes of a reactive macrocyclic receptor molecule
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 949-951
- https://doi.org/10.1039/c39780000949
Abstract
The macrocyclic molecular catalyst (1) complexes primary ammonium ester salts and displays enhanced rates of intramolecular thiolysis of the bound substrates with structural selectivity for dipeptide esters and high chiral recognition for the (L) antipode of the enantiomeric glycyl–phenyl–alanine esters.This publication has 2 references indexed in Scilit:
- Cyclic Polyether-Protonated Organic Amine Binding: Significance in Enzymatic and Ion Transport ProcessesScience, 1978
- A catalyst for ester hydrolysis showing electrostatic and hydrophobic binding propertiesCanadian Journal of Chemistry, 1976