Silicon-tethered radical cyclization and intramolecular Diels–Alder strategies are combined to provide a ready route to highly functionalized decalins
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 762-764
- https://doi.org/10.1039/c39930000762
Abstract
Stereoselective addition of carbon branches at C(1) and C(2) of L-rhamnal is achieved via silicon-mediated radical procedures, and the product is readily processed to give a hex-2-enopyranosid-4-ulose whose intramolecular Diels–Alder reaction has been examined.Keywords
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