Rapid-pair-enhanced diffusion in α-Zr and its integration into the point-defect scenario in h.c.p. metals
- 1 May 1991
- journal article
- research article
- Published by Informa UK Limited in Philosophical Magazine A
- Vol. 63 (5), 897-913
- https://doi.org/10.1080/01418619108213923
Abstract
After a brief review of our present knowledge on intrinsic point defects in h.c.p. metals, an interpretation of self-diffusion and foreign-atom diffusion in both the bulk and the grain boundaries of α-Zr is presented. It is demonstrated that rapidly diffusing foreign-atom–vacancy pairs play an outstanding role. In particular, Fe-atom–vacancy pairs control not only the bulk and grain-boundary diffusion of Fe but also the bulk self-diffusion in α-Zr. Atomistic models of the configurations, the formation and the diffusion of rapid foreign-atom–vacancy pairs are proposed. Finally, it is concluded that, on the one hand, α-Zr shows the anomaly of rapid-pairenhanced diffusion whereas, on the other hand, isolated monovacancies in α-Zr behave normally. For instance, they undergo long-range migration in the recovery stage IV (450–550 K) in accordance with the so-called two-interstitial model.Keywords
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