A homoleptic tetravalent cerium silylamide
- 1 January 2013
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 49 (1), 87-89
- https://doi.org/10.1039/c2cc37404h
Abstract
Treatment of Ce[N(SiHMe2)2]3(thf)2 with the chlorinating agents PhICl2, Ph3CCl or C2Cl6 gave the homoleptic Ce(IV) silylamide Ce[N(SiHMe2)2]4. When performed in the absence of donating (solvent) molecules, the trivalent cluster Ce5[N(SiHMe2)2]8Cl7 was isolated.Keywords
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