A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore
- 16 December 2009
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 132 (1), 30-31
- https://doi.org/10.1021/ja908794n
Abstract
All-trans retinal efficiently diffused into the pore of a porous coordination network consisting of ZnI2 and an electron-deficient triazine-cored ligand. Enclathrated retinal was isomerized into the 13-cis form and easily replaced with all-trans retinal in solution, thus revealing the catalysis of retinal isomerization by the porous network.This publication has 34 references indexed in Scilit:
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