Resonance Raman study of linear carbon chains formed by the heat treatment of double-wall carbon nanotubes
- 25 May 2006
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 73 (19), 193408
- https://doi.org/10.1103/physrevb.73.193408
Abstract
We study the resonance behavior of the unusual Raman feature known as the coalescence-inducing mode (CIM), observed at , in samples of double-wall carbon nanotubes annealed at high temperatures. Resonance Raman spectra taken with different laser energies show that the intensity of the CIM band exhibits a maximum around . By comparing the resonance Raman experimental results with first-principles calculations for the vibrational frequency and the energy gap, we propose that the CIM feature is associated with short carbon chains with an odd number of atoms, interconnecting the nanotube surfaces.
Keywords
This publication has 11 references indexed in Scilit:
- Raman scattering study for heat-treated carbon nanotubes: The origin of ≈1855cm−1 Raman bandChemical Physics Letters, 2006
- Bond-length alternation and charge transfer in a linear carbon chain encapsulated within a single-walled carbon nanotubePhysical Review B, 2005
- Atomic Nanotube Welders: Boron Interstitials Triggering Connections in Double-Walled Carbon NanotubesNano Letters, 2005
- ‘Buckypaper’ from coaxial nanotubesNature, 2005
- Synthesis and Raman characterization of boron-doped single-walled carbon nanotubesCarbon, 2005
- Carbon Nanowire Made of a Long Linear Carbon Chain Inserted Inside a Multiwalled Carbon NanotubePhysical Review Letters, 2003
- Second-order harmonic and combination modes in graphite, single-wall carbon nanotube bundles, and isolated single-wall carbon nanotubesPhysical Review B, 2002
- First-principles computation of material properties: the ABINIT software projectComputational Materials Science, 2002
- Probing Phonon Dispersion Relations of Graphite by Double Resonance Raman ScatteringPhysical Review Letters, 2001
- Vibrational analysis for short carbon chains with alternating and cumulenic structureSynthetic Metals, 1995