Stereochemical Control in the Anionic Polymerization of β-Butyrolactone Initiated with Alkali-Metal Alkoxides
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Macromolecules
- Vol. 29 (11), 3773-3777
- https://doi.org/10.1021/ma951888s
Abstract
No abstract availableKeywords
This publication has 29 references indexed in Scilit:
- Polylactones. 28. Syndiotactic Poly(.beta.-D,L-hydroxybutyrate) by Ring-Opening Polymerization of .beta.-D,L-Butyrolactone with Butyltin MethoxidesMacromolecules, 1994
- Syndiospecific ring-opening polymerization of .beta.-butyrolactone to form predominantly syndiotactic poly(.beta.-hydroxybutyrate) using tin(IV) catalystsMacromolecules, 1993
- Ring-opening polymerization of optically active .beta.-butyrolactone using distannoxane catalysts: synthesis of high-molecular-weight poly(3-hydroxybutyrate)Macromolecules, 1993
- Poly(β-hydroxybutyrate) stereoisomers: a model study of the effects of stereochemical and morphological variables on polymer biological degradabilityMacromolecules, 1992
- Thermal properties and stereoregularity of poly(3-hydroxybutyrate) prepared from optically active .beta.-butyrolactone with a zinc-based catalystMacromolecules, 1991
- What is the real mechanism of anionic polymerization of β-lactones by potassium alkoxides? A critical approachMacromolecules, 1991
- Novel polymerization of β-butyrolactone initiated by potassium naphthalenide in the presence of a crown ether or a cryptandMacromolecules, 1991
- Stereochemistry of the ring-opening polymerization of (S)-.beta.-butyrolactoneMacromolecules, 1990
- Solvated electrons, and not potassium (K-) anions, the initial products of dissolution of potassium by solutions of crown ethersThe Journal of Physical Chemistry, 1984
- 13C-NMR Spectroscopy of Poly(β-substituted β-propiolactone)s. Tacticity Recognition in 1,5-Substituted Polymer System and Stereospecific Contact of Shift ReagentMacromolecules, 1978