Spin-crossover in [Fe(3-bpp)2][BF4]2 in different solvents – A dramatic stabilisation of the low-spin state in water
- 1 January 2011
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 40 (45), 12021-12024
- https://doi.org/10.1039/c1dt10620a
Abstract
The temperature of spin-crossover in [Fe(3-bpp)2][BF4]2 (3-bpp = 2,6-di{pyrazol-3-yl}pyridine) tends to increase in associating solvents. In particular, T½ shifts to 60–70 K higher temperature in water compared to organic solvents.This publication has 23 references indexed in Scilit:
- Iron Spin-Crossover compounds: from fundamental studies to practical applicationsDalton Transactions, 2009
- Trapping and manipulating excited spin states of transition metal compoundsChemical Society Reviews, 2007
- Control of Magnetic Properties through External StimuliAngewandte Chemie, 2007
- Solution Characterization of the Iron(II) Bis(1,4,7-Triazacyclononane) Spin-Equilibrium ReactionInorganic Chemistry, 2001
- The ligand field 1A1-5T2 spin crossover with iron(II) encapsulated in hexa-amine cagesPolyhedron, 1994
- Spin-crossover complexes in solution. III. Substituent- and solvent effects on the spin-equilibrium of 4-substituted iron(II)-2,6-bis-(benzimidazol-2?-yl)-pyridine systemsMonatshefte für Chemie / Chemical Monthly, 1994
- Structural, Magnetic and Mössbauer Spectral Studies of Salts of Bis[2,6-bis(pyrazol-3-yl)pyridine]iron(II)—a Spin Crossover SystemAustralian Journal of Chemistry, 1994
- Spin-crossover complexes in solution, II solvent effects on the high spin-low spin-equilibrium of [Fe(bzimpy)2](ClO4)2Monatshefte für Chemie / Chemical Monthly, 1993
- Variable spin iron(III) chelates with hexadentate ligands derived from triethylenetetramine and various salicylaldehydes. Synthesis, characterization, and solution state studies of a new 2T .dblarw. 6A spin equilibrium systemJournal of the American Chemical Society, 1976
- Substituent effects on the spin equilibrium observed with hexadentate ligands on iron(II)Journal of the American Chemical Society, 1975