Colloidal Synthesis of Quantum Confined Single Crystal CsPbBr3 Nanosheets with Lateral Size Control up to the Micrometer Range
Open Access
- 6 June 2016
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 138 (23), 7240-7243
- https://doi.org/10.1021/jacs.6b03166
Abstract
We report the non-templated colloidal synthesis of single crystal CsPbBr3 perovskite nanosheets with lateral sizes up to a few µm and with thickness of just a few unit cells (i.e. below 5 nm), hence in the strong quantum confinement regime, by introducing short ligands (octanoic acid and octylamine) in the synthesis together with longer ones (oleic acid and oleylamine). The lateral size is tunable by varying the ratio of shorter ligands over longer ligands, while the vertical dimension is mainly unaffected by this parameter and stays practically constant at 3 nm in all the syntheses conducted at short-to-long ligands volumetric ratio below 0.67. Beyond this ratio, control over the thickness is lost and a multimodal thickness distribution is observed.Keywords
Funding Information
- European Research Council (614897)
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