Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal–organic framework NU-111
- 21 February 2013
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 49 (29), 2992-2994
- https://doi.org/10.1039/c3cc40819a
Abstract
We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within ≈75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g−1 and 284 cc(STP) per cc at 65 bar. Adsorption of CO2 and H2 is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.Keywords
This publication has 38 references indexed in Scilit:
- Methane storage in advanced porous materialsChemical Society Reviews, 2012
- Hydrogen Storage in Metal–Organic FrameworksChemical Reviews, 2011
- Adsorption Sites and Binding Nature of CO2 in Prototypical Metal−Organic Frameworks: A Combined Neutron Diffraction and First-Principles StudyThe Journal of Physical Chemistry Letters, 2010
- Soft porous crystalsNature Chemistry, 2009
- High-Capacity Methane Storage in Metal−Organic Frameworks M2(dhtp): The Important Role of Open Metal SitesJournal of the American Chemical Society, 2009
- Enhanced H2 Adsorption in Isostructural Metal−Organic Frameworks with Open Metal Sites: Strong Dependence of the Binding Strength on Metal IonsJournal of the American Chemical Society, 2008
- Nature and Tunability of Enhanced Hydrogen Binding in Metal−Organic Frameworks with Exposed Transition Metal SitesThe Journal of Physical Chemistry C, 2008
- Hybrid porous solids: past, present, futureChemical Society Reviews, 2007
- Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn2+ Coordination SitesJournal of the American Chemical Society, 2006
- Reticular synthesis and the design of new materialsNature, 2003