A Thermally Stable Gold(III) Hydride: Synthesis, Reactivity, and Reductive Condensation as a Route to Gold(II) Complexes
- 20 September 2012
- journal article
- review article
- Published by Wiley in Angewandte Chemie
- Vol. 51 (42), 10643-10646
- https://doi.org/10.1002/anie.201206468
Abstract
Going for gold: The first thermally stable gold(III) hydride [(C N C)*AuH] is presented. It undergoes regioselective insertions with allenes to give gold(III) vinyl complexes, and reductive condensation with [(C N C)*AuOH] to the air‐stable AuII product, [(C N C)*2Au2], with a short nonbridged gold–gold bond.Keywords
This publication has 94 references indexed in Scilit:
- Silver-free Gold(I) Catalysts for Organic TransformationsZeitschrift für Naturforschung B, 2011
- A review of the use of gold catalysts in selective hydrogenation reactions Lynsey McEwanaGold Bulletin, 2010
- Eintopfsynthese von Menthol in Gegenwart eines hoch diastereoselektiven Au/MgF2‐KatalysatorsAngewandte Chemie, 2010
- A Reactivity-Driven Approach to the Discovery and Development of Gold-Catalyzed Organic ReactionsSynlett, 2010
- Ligand Effects in Homogeneous Au CatalysisChemical Reviews, 2008
- Mechanistic analogies and differences between gold- and palladium-supported Schiff base complexes as hydrogenation catalysts: A combined kinetic and DFT studyJournal of Catalysis, 2008
- Gold Nanoparticles and Gold(III) Complexes as General and Selective Hydrosilylation CatalystsAngewandte Chemie, 2007
- Enantioselective hydrogenation of alkenes and imines by a gold catalystChemical Communications, 2005
- Gold Is Noble but Gold Hydride Anions Are StableAngewandte Chemie, 2003
- Hydride und Iodide des GoldesAngewandte Chemie, 2002