Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen by Using a Water‐Soluble Iridium Complex and Flavin Mononucleotide
Open Access
- 25 October 2013
- journal article
- research article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 52 (47), 12327-12331
- https://doi.org/10.1002/anie.201307273
Abstract
H2, O2 to H2O2: The direct synthesis of hydrogen peroxide from hydrogen and oxygen in water has been made possible by using an iridium(III) complex, [IrIII(Cp*)(4-(1H-pyrazol-1-yl-κN2)benzoic acid-κC3)(H2O)]2SO4, and flavin mononucleotide. This method gives hydrogen peroxide with a high turnover number (847) and yield (19.2 %) under normal pressure and at room temperature.Keywords
This publication has 49 references indexed in Scilit:
- Highly dispersed encapsulated AuPd nanoparticles on ordered mesoporous carbons for the direct synthesis of H2O2 from molecular oxygen and hydrogenChemical Communications, 2012
- Hydrogen peroxide as a sustainable energy carrier: Electrocatalytic production of hydrogen peroxide and the fuel cellElectrochimica Acta, 2012
- Synthesis of Pd nanoparticles on heteropolyacid-supported silica by a photo-assisted deposition method: an active catalyst for the direct synthesis of hydrogen peroxideRSC Advances, 2011
- Some insights on the negative effect played by silylation of functionalized commercial silica in the direct synthesis of hydrogen peroxideCatalysis Today, 2010
- Recent advances in catalytic asymmetric epoxidation using the environmentally benign oxidant hydrogen peroxide and its derivativesChemical Society Reviews, 2010
- Direct Synthesis of H2O2 from H2 and O2 over Gold, Palladium, and Gold–Palladium Catalysts Supported on Acid‐Pretreated TiO2Angewandte Chemie-International Edition, 2009
- Effect of Halide and Acid Additives on the Direct Synthesis of Hydrogen Peroxide using Supported Gold–Palladium CatalystsChemSusChem, 2009
- Contributions of the 8-Methyl Group to the Vibrational Normal Modes of Flavin Mononucleotide and Its 5-Methyl Semiquinone RadicalThe Journal of Physical Chemistry A, 2008
- Direct synthesis of H2O2 from O2 and H2 over precious metal loaded TS-1 in CO2Green Chemistry, 2007
- Anwendung von Übergangsmetallkomplexen zum Bleichen von Textilien und HolzpulpeAngewandte Chemie, 2005