Synthesis of Vinyl Boronates from Aldehydes by a Practical Boron–Wittig Reaction
- 23 March 2015
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 17 (7), 1708-1711
- https://doi.org/10.1021/acs.orglett.5b00480
Abstract
A highly stereoselective boron-Wittig reaction between stable and readily accessible 1,1-bis(pinacolboronates) and aldehydes furnishes a variety of synthetically useful di- and trisubstituted vinyl boronate esters.Keywords
Funding Information
- National Institute of General Medical Sciences (GM 059417)
This publication has 54 references indexed in Scilit:
- Selection of boron reagents for Suzuki–Miyaura couplingChemical Society Reviews, 2013
- Recent developments in asymmetric multicomponent reactionsChemical Society Reviews, 2012
- Boronic AcidsPublished by Wiley ,2011
- Boronic Acids and Esters in the Petasis-Borono Mannich Multicomponent ReactionChemical Reviews, 2010
- Alkoxydienes via Copper-Promoted Couplings: Utilizing an Alkyne EffectOrganic Letters, 2010
- Copper-Promoted Coupling of Vinyl Boronates and Alcohols: A Mild Synthesis of Allyl Vinyl EthersJournal of the American Chemical Society, 2010
- Organoboranes for SynthesesPublished by American Chemical Society (ACS) ,2001
- Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998Journal of Organometallic Chemistry, 1999
- Palladium-Catalyzed Cross-Coupling Reactions of Organoboron CompoundsChemical Reviews, 1995
- Boronic Esters in Stereodirected SynthesisTetrahedron, 1989