Formulation of Thermally Cured Organic-Inorganic Superhydrophilic Coating for Antifogging Optical Application
- 22 January 2007
- journal article
- optical properties-and-devices
- Published by Informa UK Limited in Molecular Crystals and Liquid Crystals
- Vol. 463 (1), 117/[399]-129/[411]
- https://doi.org/10.1080/15421400601027668
Abstract
Formation of coatings with combined properties of being superhydrophilic/superhydrophobic are of immense applications in the field of optics. In our present work, we have developed a transparent, organic/inorganic hybrid coating by mixing appropriate ratios of organic silanol coupling agents and monoacrylates to impart strong adhesion to the substrate, and inorganic components comprising of a hybrid mixture of silica-titania, and certain vinyl components as well as hydrophilic surfactants for improved antifogging behavior. Polycarbonate lens or glass slides, as substrates were dip coated into the hybrid precursor solution at a suitable withdrawal rate of 5 cm/min to form uniform and crack free film of thickness 458 nm. The sequential process of drying of the coated films involved thermal curing at varied temperature and time in the presence of an appropriate thermal initiator, dicumyl peroxide. The surface chemistry and thermal behavior along with the superhydrophilicty and fogging behavior of the coated substrates were assessed by respective ATR-IR, 29Si NMR, TGA/DSC analysis and AFM measurements. The remarkabale observation was that the composite of organic-inorganic mixture exhibited desired properties of being superhydrophilic as well as antifogging on the substrate by curing at appropriate temperature of 50°C for 24 hr and 120°C for 8 hr, respectively.Keywords
This publication has 13 references indexed in Scilit:
- Preparation and properties of alkoxy(methyl)silsesquioxanes as coating agentsJournal of Polymer Science Part A: Polymer Chemistry, 2004
- Preparation and characterization of hydrophobic organic–inorganic composite thin films of PMMA/SiO2/TiO2 with low friction coefficientApplied Surface Science, 2004
- Enhanced effect and mechanism of SiO2 addition in super-hydrophilic property of TiO2 filmsSurface and Coatings Technology, 2003
- Sol–gel: a new tool for coatings chemistryProgress in Organic Coatings, 2002
- Novel sodium sulfonate-functionalized poly(ether ether ketone)s derived from 4,4′-thiodiphenolPolymer, 2001
- Abrasion resistance in the Tumble test of sol–gel hybrid coatings for ophthalmic plastic lensesMaterials Letters, 2000
- Photocatalytic activity and photoinduced hydrophilicity of titanium dioxide coated glassThin Solid Films, 1999
- Super‐Water‐Repellent Al2O3 Coating Films with High TransparencyJournal of the American Ceramic Society, 1997
- New coating materials prepared by radiation-induced polymerization. II. Study on the polymerization mechanism of mar-resistant coating compositionJournal of Applied Polymer Science, 1978
- New coating materials prepared by radiation‐induced polymerization. I. Mar‐resistant coating composition and propertiesJournal of Applied Polymer Science, 1978