A Nanoring−Nanosphere Molecule, {Mo214V30}: Pushing the Boundaries of Controllable Inorganic Structural Organization at the Molecular Level
- 1 April 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (16), 5336-5337
- https://doi.org/10.1021/ja060886s
Abstract
A controlled, Raman-monitored chemical reduction of a molybdate and vanadate mixture affords a new type of molybdenum-oxide-based cluster showing an unprecedented level of inorganic structural organization. The cluster incorporates two nanosized substructures (a ring and a sphere) in an open clam-like assembly. Multiple methods indicate that the nanoring contains delocalized electrons and the nanosphere contains localized but interacting electrons.Keywords
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