First spectroscopic evidence for molecular HCl on a liquid surface with sum frequency generation
- 15 June 1998
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 108 (23), 9817-9820
- https://doi.org/10.1063/1.476456
Abstract
Sum frequency generation spectroscopy has been used to obtain the vibrational spectrum of HCl on the surface of a liquid. HCl was studied on the surface of 96 wt % 12 M HCl solution, liquid HCl and glass, of which only liquid HCl produces a resonant signal. Implications for the form of HCl on surfaces and the reactions in the atmosphere are discussed.
Keywords
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