Spin Crossover in a Four-Coordinate Iron(II) Complex
- 2 March 2011
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 133 (11), 3824-3827
- https://doi.org/10.1021/ja2003473
Abstract
The four-coordinate iron(II) phosphoraniminato complex PhB(MesIm)3Fe−N═PPh3 undergoes an S = 0 to S = 2 spin transition with TC = 81 K, as determined by variable-temperature magnetic measurements and Mössbauer spectroscopy. Variable-temperature single-crystal X-ray diffraction revealed that the S = 0 to S = 2 transition is associated with an increase in the Fe−C and Fe−N bond distances and a decrease in the N−P bond distance. These structural changes have been interpreted in terms of electronic structure theory.This publication has 17 references indexed in Scilit:
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