Development of Dispersed-Catalyst/NSTF Hybrid Electrode
Open Access
- 1 January 2012
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 159 (11), F676-F682
- https://doi.org/10.1149/2.023211jes
Abstract
Ultrathin electrodes, such as the 3M Nanostructured Thin Film (NSTF) electrode, provide a plausible pathway to reduce platinum cost in low temperature fuel cells. However, several operational shortcomings, involving relatively poor electrode proton conduction and tendencies to collect water in the cathode, were observed in our fuel cell tests. This can be greatly mitigated when a few-micron thick dispersed-catalyst layer is placed adjacent to the NSTF layer, forming a dispersed-catalyst/NSTF hybrid electrode. This dispersed-catalyst layer is also called the “interlayer” because it is located between the NSTF layer and the microporous layer of the cathode diffusion medium. In this study, development of the hybrid electrode was pursued. Emphasis on developing lab-scale fabrication methods that can easily translate to roll-to-roll manufacturing process was a key element of the hybrid electrode development. The fuel cell performance of the electrode showed high sensitivity to fabrication methods. When the dispersed-catalyst layer was coated directly on the NSTF electrode, voltage at high current density dropped significantly. The voltage loss was surmised to be caused by ionomer seepage into the NSTF layer during the coating process. This voltage loss could be eliminated by placing the dispersed-catalyst layer on the gas-diffusion layer and then located adjacent to the NSTF cathode. Interaction between the dispersed-catalyst and NSTF layers and how it affects the fuel cell performance is discussed.Keywords
This publication has 38 references indexed in Scilit:
- Electrochemical and Microstructural Evaluation of Aged Nanostructured Thin Film Fuel Cell ElectrocatalystJournal of the Electrochemical Society, 2011
- Carbon-Support Requirements for Highly Durable Fuel Cell OperationPublished by Springer Science and Business Media LLC ,2009
- Dissolution and Stabilization of Platinum in Oxygen CathodesPublished by Springer Science and Business Media LLC ,2009
- Instability of Supported Platinum Nanoparticles in Low-Temperature Fuel CellsTopics in Catalysis, 2007
- Understanding and approaches for the durability issues of Pt-based catalysts for PEM fuel cellJournal of Power Sources, 2007
- High voltage stability of nanostructured thin film catalysts for PEM fuel cellsJournal of Power Sources, 2006
- Stop-Start and High-Current Durability Testing of Nanostructured Thin Film Catalysts for PEM Fuel CellsECS Transactions, 2006
- Durability Aspects of Nanostructured Thin Film Catalysts for PEM Fuel CellsECS Transactions, 2006
- Structural characteristics of a uniquely nanostructured organic thin filmJournal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, 1995
- Postdeposition growth of a uniquely nanostructured organic film by vacuum annealingJournal of Vacuum Science & Technology A, 1994