Synthesis of a β-diiminate iridium tetrahydride for arene C–H bond activation
- 27 February 2004
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 764-765
- https://doi.org/10.1039/b315817a
Abstract
The preparation of the iridium tetrahydride (iPrBDI)IrH4 {BDI = ArNC(Me)CH(Me)CNAr, Ar = 2,6-iPr2C6H3} and its activity in the catalytic C–H activation of arenes is described.Keywords
This publication has 18 references indexed in Scilit:
- β-Diiminate Platinum Complexes for Alkane DehydrogenationJournal of the American Chemical Society, 2003
- Novel synthesis of enamines by iridium-catalyzed dehydrogenation of tertiary aminesElectronic supplementary information (ESI) available: detailed experimental procedures and spectroscopic information. See http://www.rsc.org/suppdata/cc/b3/b304357f/Chemical Communications, 2003
- Cyclometalated Phosphine-Based Pincer Complexes: Mechanistic Insight in Catalysis, Coordination, and Bond ActivationChemical Reviews, 2003
- Cationic Ir(III) alkyl and hydride complexes: stoichiometric and catalytic CH activation by Cp∗(PMe3)Ir(R)(X) in homogeneous solutionJournal of Molecular Catalysis A: Chemical, 2002
- Understanding and exploiting C–H bond activationNature, 2002
- Minimum Energy Structure of Hydridotris(pyrazolyl)borato Iridium(V) Tetrahydride Is Not a C3v Capped OctahedronJournal of the American Chemical Society, 2001
- A Stable Three-Coordinate Rhodium(I) Olefin ComplexOrganometallics, 1998
- Deuteration Studies of Tp*IrH4 (Tp* = HB(3,5-Me2pz)3): Observation of Very Unusual 1H NMR Chemical Shift EffectsJournal of the American Chemical Society, 1994
- Assessment of the "T1 criterion" for distinguishing between classical and nonclassical transition-metal hydrides: hydride relaxation rates in tris(triarylphosphine)osmium tetrahydrides and related polyhydridesJournal of the American Chemical Society, 1991
- Preparation and reactions of tetrahydrido(pentamethylcyclopentadienyl)iridium: a novel iridium(V) polyhydrideOrganometallics, 1983