Few-layer MXene Ti3C2Tx (T = F, O, or OH) saturable absorber for visible bulk laser

Abstract

The novel two-dimensional MXenes have been investigated in the photonics field in areas such as broadband nonlinearity, pulse laser generation and passive photonic diode, and so on. In this contribution, the nonlinear optical response at the visible band and the demand pulse laser generation based on MXenes was initially realized. The few-layer MXene Ti₃C₂T_x was fabricated and utilized as a saturable absorber (SA) to realize passive Q-switched visible bulk laser covering the spectral range of orange (607 nm), red (639 nm), and deep red (721 nm). At the three wavelength, the maximum average output powers and the shortest pulse widths were (111 mW, 426 ns) for 607 nm, (150 mW, 264 ns) for 639 nm, (115 mW, 328 ns) for 721 nm, respectively. Our experimental results indicate the MXene Ti₃C₂T_x SA could be an efficient and promising optical modulator in the visible domain.