Cyclohexane selective oxidation over metal–organic frameworks of MIL-101 family: superior catalytic activity and selectivity
- 16 May 2012
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 48 (54), 6812-6814
- https://doi.org/10.1039/c2cc31877f
Abstract
Mesoporous metal–organic frameworks Cr- and Fe-MIL-101 are highly efficient, true heterogeneous and recyclable catalysts for solvent-free selective oxidation of cyclohexane with molecular oxygen and/or tert-butyl hydroperoxide under mild conditions.Keywords
This publication has 36 references indexed in Scilit:
- Metal–organic frameworks as heterogeneous catalysts for oxidation reactionsCatalysis Science & Technology, 2011
- Engineering Metal Organic Frameworks for Heterogeneous CatalysisChemical Reviews, 2010
- Postsynthetic Modifications of Iron-Carboxylate Nanoscale Metal−Organic Frameworks for Imaging and Drug DeliveryJournal of the American Chemical Society, 2009
- Selective sulfoxidation of aryl sulfides by coordinatively unsaturated metal centers in chromium carboxylate MIL-101Applied Catalysis A: General, 2009
- High-Throughput Assisted Rationalization of the Formation of Metal Organic Frameworks in the Iron(III) Aminoterephthalate Solvothermal SystemInorganic Chemistry, 2008
- One step synthesis of chromium-containing periodic mesoporous organosilicas and their catalytic activity in the oxidation of cyclohexaneMicroporous and Mesoporous Materials, 2007
- Silica‐Immobilized Chromium Colloids for Cyclohexane AutoxidationAngewandte Chemie-International Edition, 2006
- Liquid phase oxidation of cyclohexane over transition metal incorporated amorphous 3D-mesoporous silicates M-TUD-1 (M=Ti, Fe, Co and Cr)Catalysis Today, 2006
- Aerobic oxidation of cyclohexane by gold nanoparticles immobilized upon mesoporous silicaCatalysis Letters, 2005
- Role of cobalt molecular sieves in the liquid-phase oxidation of cyclohexane to adipic acidJournal of the Chemical Society, Faraday Transactions, 1998