New element organic frameworks viaSuzuki coupling with high adsorption capacity for hydrophobic molecules
- 1 January 2010
- journal article
- Published by Royal Society of Chemistry (RSC) in Soft Matter
- Vol. 6 (16), 3918-3923
- https://doi.org/10.1039/c003130e
Abstract
We present new highly microporous element organic frameworks synthesized by the Pd catalyzed Suzuki coupling reaction. They show specific surface areas of up to 1380 m2 g−1 with a strong hydrophobic character. Thus, they are interesting for the adsorption of non-polar substances. By variation of the organic linkers, the modular concept of the materials in analogy to the metal–organic frameworks is demonstrated. The polymeric materials have thermal stability up to 573 K and show no decomposition in aqueous environment, allowing excellent handling and processing. They are accessible by a basic synthetic approach, and by their chemical and thermal stabilities they may provide adequate properties for applications in many fields, especially in adsorptive separation processes and storage of non-polar gases.Keywords
This publication has 28 references indexed in Scilit:
- Microporous Networks of High-Performance Polymers: Elastic Deformations and Gas Sorption PropertiesMacromolecules, 2008
- Hypercrosslinked polyanilines with nanoporous structure and high surface area: potential adsorbents for hydrogen storageJournal of Materials Chemistry, 2007
- Solution infiltration of palladium into MOF-5: synthesis, physisorption and catalytic propertiesJournal of Materials Chemistry, 2007
- Hydrogen Storage in Microporous Hypercrosslinked Organic Polymer NetworksChemistry of Materials, 2007
- Porous structure of hypercrosslinked polystyrene: State-of-the-art mini-reviewReactive and Functional Polymers, 2006
- Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storageChemical Society Reviews, 2006
- Towards Polymer‐Based Hydrogen Storage Materials: Engineering Ultramicroporous Cavities within Polymers of Intrinsic MicroporosityAngewandte Chemie, 2006
- A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface AreaScience, 2005
- Crystallized Frameworks with Giant Pores: Are There Limits to the Possible?Accounts of Chemical Research, 2005
- Functional Porous Coordination PolymersAngewandte Chemie, 2004