Degradation of Anode Supported SOFCs as a Function of Temperature and Current Load
Open Access
- 1 January 2006
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 153 (6), A1165-A1171
- https://doi.org/10.1149/1.2193400
Abstract
The degradation behavior of anode supported solid oxide fuel cells (SOFCs) was investigated as a function of operating temperature and current density. Degradation rates were defined and shown to be mainly dependent on the cell polarization. The combination of a detailed evaluation of electrochemical properties by impedance spectroscopy, in particular, and post-test microscopy revealed that cathode degradation was the dominant contribution to degradation at higher current densities and lower temperatures. The anode was found to contribute more to degradation at higher temperatures. Generally, the degradation rates obtained were lower at higher operating temperatures, even at higher current densities. A degradation rate as low as 2%∕1000h2%∕1000h was observed at 1.7A∕cm21.7A∕cm2 and 950°C950°C over an operating period of 1500h1500h .Keywords
This publication has 16 references indexed in Scilit:
- Sintering and grain growth of (La,Sr)MnO3 electrodes of solid oxide fuel cells under polarizationSolid State Ionics, 2005
- Performance Variability of La(Sr)FeO[sub 3] SOFC Cathode with Pt, Ag, and Au Current CollectorsJournal of the Electrochemical Society, 2005
- Effect of Polarization on and Implications for Characterization of LSM-YSZ Composite CathodesElectrochemical and Solid-State Letters, 2004
- Effects of impurities on microstructure in Ni/YSZ–YSZ half-cells for SOFCSolid State Ionics, 2003
- Long-Term Tests of DK-SOFC CellsECS Proceedings Volumes, 2003
- Structure - Property Relationships of Ni/YSZ and Ni/(YSZ+TiO2) CermetsFuel Cells, 2001
- Impedance of Solid Oxide Fuel Cell LSM/YSZ Composite CathodesJournal of the Electrochemical Society, 2001
- Statistical geometry of reaction space in porous cermet anodes based on ion-conducting electrolytes Patterns of degradationSolid State Ionics, 1999
- Oxygen transfer processes in (La,Sr)MnO3/Y2O3-stabilized ZrO2 cathodes: an impedance spectroscopy studySolid State Ionics, 1998
- Electrode Properties of Sr‐Doped LaMnO3 on Yttria‐Stabilized Zirconia: II. Electrode KineticsJournal of the Electrochemical Society, 1997