Highly Regioselective Ir-Catalyzed β-Borylation of Porphyrins via C−H Bond Activation and Construction of β−β-Linked Diporphyrin
- 12 May 2005
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (23), 8264-8265
- https://doi.org/10.1021/ja051073r
Abstract
Highly regioselective borylation of 5,15-diaryl- and 5,10,15-triarylporphyrins has been achieved by the reaction with bis(pinacolato)diborane under iridium catalysis. Borylated porphyrins are a useful building block for constructing porphyrin arrays, hence offering an effective route to beta-functionalized porphyrins.This publication has 11 references indexed in Scilit:
- Synthesis of meso-meso Linked Hybrid Porphyrin Arrays by Pd-Catalyzed Cross-Coupling ReactionOrganic Letters, 2001
- Facile Synthesis ofβ-Derivatized Porphyrins—Structural Characterization of aβ -β-Bis-PorphyrinAngewandte Chemie-International Edition, 2000
- Synthesis of directly meso-meso linked bisporphyrins using organolithium reagentsTetrahedron Letters, 1999
- Suzuki Porphyrins: New Synthons for the Fabrication of Porphyrin-Containing Supramolecular AssembliesJournal of the American Chemical Society, 1998
- Facilemeso Functionalization of Porphyrins by Nucleophilic Substitution with Organolithium ReagentsAngewandte Chemie-International Edition, 1998
- meso, meso‐Linked Porphyrin ArraysAngewandte Chemie-International Edition, 1997
- Synthesis of novel porphyrin arrays directly-linked through the meso-carbonsTetrahedron Letters, 1996
- Palladium-Catalyzed Cross-Coupling Reactions of Organoboron CompoundsChemical Reviews, 1995
- Photostimulated reaction of 1-haloadamantane and 9-bromotriptycene with nucleophiles. A nucleophilic substitution by SRN1 at the bridgehead positionThe Journal of Organic Chemistry, 1984
- Exciton and electron interaction in covalently-linked dimeric porphyrinsCanadian Journal of Chemistry, 1978