Transition-Metal-Free Oxyarylation of Alkenes with Aryl Diazonium Salts and TEMPONa
- 28 September 2012
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 134 (40), 16516-16519
- https://doi.org/10.1021/ja307638u
Abstract
The reaction of readily available TEMPO-Na with aryl diazonium salts allows for clean generation of the corresponding aryl radicals along with TEMPO. Aryl radical addition to alkenes with subsequent TEMPO trapping provides the corresponding oxyarylation products in good to excellent yields. These experimentally easy to conduct transformations occur in the absence of any transition metal under mild conditions, and the process shows broad functional group compatibility.This publication has 69 references indexed in Scilit:
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