Resolution of chiral polyoxoanion [P2Mo18O62]6− with histidine
- 1 January 2010
- journal article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 12 (7), 2044-2046
- https://doi.org/10.1039/c001160f
Abstract
The classical Dawson-type racemic polyoxoanions [P2Mo18O62]6− have been separated in aqueous solution with L,D-histidine, respectively. Two enantiomerically pure compounds: H3(L-HC6H9N3O2)3[P2Mo18O62]·20H2O (1a), H3(D-HC6H9N3O2)3[P2Mo18O62]·20H2O (1b), have been synthesized.Keywords
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