Nanoscale Interface Modification of LiCoO2by Al2O3Atomic Layer Deposition for Solid-State Li Batteries
- 1 January 2012
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 159 (7), A1120-A1124
- https://doi.org/10.1149/2.085207jes
Abstract
Cycle stability of solid-state lithium batteries (SSLBs) using a LiCoO2 cathode is improved by atomic layer deposition (ALD) on active material powder with Al2O3. SSLBs with LiCoO2/Li3.15Ge0.15P0.85S4/77.5Li2S-22.5P2S5/Li structure were constructed and tested by charge-discharge cycling at a current density of 45 μA cm−2 with a voltage window of 3.3 ∼ 4.3 V (vs. Li/Li+). Capacity degradation during cycling is suppressed dramatically by employing Al2O3 ALD-coated LiCoO2 in the composite cathode. Whereas only 70% of capacity retention is achieved for uncoated LiCoO2 after 25 cycles, 90% of capacity retention is observed for LiCoO2 with ALD Al2O3 layers. Electrochemical impedance spectroscopy (EIS) and transmission electron microscopy (TEM) studies show that the presence of ALD Al2O3 layers on the surface of LiCoO2 reduces interfacial resistance development between LiCoO2 and solid state electrolyte (SSE) during cycling.Keywords
This publication has 19 references indexed in Scilit:
- Ceramic and polymeric solid electrolytes for lithium-ion batteriesJournal of Power Sources, 2010
- Electrochemical performance of all-solid-state lithium secondary batteries improved by the coating of Li2O–TiO2 films on LiCoO2 electrodeJournal of Power Sources, 2010
- Interfacial Observation between LiCoO2 Electrode and Li2S−P2S5 Solid Electrolytes of All-Solid-State Lithium Secondary Batteries Using Transmission Electron MicroscopyChemistry of Materials, 2009
- All-solid-state lithium secondary batteries with oxide-coated LiCoO2 electrode and Li2S–P2S5 electrolyteJournal of Power Sources, 2008
- Interfacial modification for high-power solid-state lithium batteriesSolid State Ionics, 2008
- Building better batteriesNature, 2008
- Enhancement of the High‐Rate Capability of Solid‐State Lithium Batteries by Nanoscale Interfacial ModificationAdvanced Materials, 2006
- Effect of Al2O3 coating on electrochemical performance of LiCoO2 as cathode materials for secondary lithium batteriesJournal of Power Sources, 2004
- All-solid-state lithium secondary batteries using a layer-structured LiNi0.5Mn0.5O2 cathode materialJournal of Power Sources, 2003
- Electrochemical Stability of Thin-Film LiCoO2 Cathodes by Aluminum-Oxide CoatingChemistry of Materials, 2003