T‐Nb2O5/C Nanofibers Prepared through Electrospinning with Prolonged Cycle Durability for High‐Rate Sodium–Ion Batteries Induced by Pseudocapacitance
- 12 October 2017
- Vol. 13 (46)
- https://doi.org/10.1002/smll.201702588
Abstract
Homogeneous ultrasmall T‐Nb2O5 nanocrystallites encapsulated in 1D carbon nanofibers (T‐Nb2O5/CNFs) are prepared through electrospinning followed by subsequent pyrolysis treatment. In a Na half‐cell configuration, the obtained T‐Nb2O5/CNFs with the merits of unique microstructures and inherent pseudocapacitance, deliver a stable capacity of 150 mAh g−1 at 1 A g−1 over 5000 cycles. Even at an ultrahigh charge–discharge rate of 8 A g−1, a high reversible capacity of 97 mAh g−1 is still achieved. By means of kinetic analysis, it is demonstrated that the larger ratio of surface Faradaic reactions of Nb2O5 at high rates is the major factor to achieve excellent rate performance. The prolonged cycle durability and excellent rate performance endows T‐Nb2O5/CNFs with potentials as anode materials for sodium‐ion batteries.Keywords
Funding Information
- Science and Technology Commission of Shanghai Municipality (16PTSYJC00010)
- National Natural Science Foundation of China (21773126)
This publication has 35 references indexed in Scilit:
- Direct atomic-scale confirmation of three-phase storage mechanism in Li4Ti5O12 anodes for room-temperature sodium-ion batteriesNature Communications, 2013
- Sodium Storage and Transport Properties in Layered Na2Ti3O7 for Room‐Temperature Sodium‐Ion BatteriesAdvanced Energy Materials, 2013
- Na2Ti3O7: an intercalation based anode for sodium-ion battery applicationsJournal of Materials Chemistry A, 2012
- Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteriesNanoscale, 2012
- The Effect of Crystallinity on the Rapid Pseudocapacitive Response of Nb2O5Advanced Energy Materials, 2011
- Electrical Energy Storage for the Grid: A Battery of ChoicesScience, 2011
- Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard‐Carbon Electrodes and Application to Na‐Ion BatteriesAdvanced Functional Materials, 2011
- Challenges for Rechargeable Li BatteriesChemistry of Materials, 2009
- Nb 3d and O 1s core levels and chemical bonding in niobatesJournal of Electron Spectroscopy and Related Phenomena, 2005
- Electrospinning of Nanofibers: Reinventing the Wheel?Advanced Materials, 2004