Correlation Energy in Atomic Systems. IV. Degeneracy Effects
- 15 April 1966
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 44 (8), 3050-3053
- https://doi.org/10.1063/1.1727179
Abstract
The degeneracy effects in the isoelectronic series of the first‐row atoms are analyzed. The near‐degenerate configurations 1s22s22p2 and 1s22s02pn+2 are computed within the framework of a two‐configuration SCF technique. The newly obtained correlation energy diagram indicates a remarkable simplicity in its structure.Keywords
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