Au-Containing All-Carbon 1,3-Dipoles: Generation and [3+2] Cycloaddition Reactions
- 28 August 2008
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 130 (38), 12598-12599
- https://doi.org/10.1021/ja804690u
Abstract
A novel approach to generate Au-containing all-carbon 1,3-dipoles is developed via an unprecedented migration−fragmentation of ketals/acetals. These in situ generated dipoles undergo rapid [3+2] cycloaddition under mild conditions with various enones/enals, electron-rich aromatic aldehydes, and N-benzylindole, leading to flexible formation of highly functionalized dihydrofurans and cyclopentenes.This publication has 20 references indexed in Scilit:
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