On the Shape of Surface Nanobubbles
- 16 September 2009
- journal article
- Published by American Chemical Society (ACS) in Langmuir
- Vol. 26 (1), 260-268
- https://doi.org/10.1021/la902121x
Abstract
Previous AFM experiments on surface nanobubbles have suggested an anomalously large contact angle θ of the bubbles (typically ∼160° measured through the water) and a possible size dependence θ(R). Here we determine θ(R) for nanobubbles on smooth, highly oriented pyrolytic graphite (HOPG) with a variety of different cantilevers. It is found that θ(R) is constant within experimental error, down to bubbles as small as R = 20 nm, and is equal to 119 ± 4°. This result, which is the lowest contact angle for surface nanobubbles found so far, is very reproducible and independent of the cantilever type used, provided that the cantilever is clean and the HOPG surface is smooth. In contrast, we find that, for a particular set of cantilevers, the surface can become relatively rough because of precipitated matter from the cantilever onto the substrate, in which case larger nanoscopic contact angles (∼150°) show up. In addition, we address the issue of the set-point dependence. Once the set-point ratio is below roughly 95%, the obtained nanobubble shape changes and depends on both nanobubble size and cantilever properties (spring constant, material, and shape).Keywords
This publication has 40 references indexed in Scilit:
- Characterization of Nanobubbles on Hydrophobic Surfaces in WaterLangmuir, 2007
- Removal of Induced Nanobubbles from Water/Graphite Interfaces by Partial DegassingLangmuir, 2006
- Electrochemically Controlled Formation and Growth of Hydrogen NanobubblesLangmuir, 2006
- Physical Properties of Nanobubbles on Hydrophobic Surfaces in Water and Aqueous SolutionsLangmuir, 2006
- Nanobubbles give evidence of incomplete wetting at a hydrophobic interfaceJournal of Colloid and Interface Science, 2004
- Images of Nanobubbles on Hydrophobic Surfaces and Their InteractionsPhysical Review Letters, 2001
- Nanobubbles on solid surface imaged by atomic force microscopyJournal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, 2000
- Nano Bubbles on a Hydrophobic Surface in Water Observed by Tapping-Mode Atomic Force MicroscopyLangmuir, 2000
- Interaction Forces between Hydrophobic Surfaces. Attractive Jump as an Indication of Formation of “Stable” SubmicrocavitiesThe Journal of Physical Chemistry B, 2000
- Forces Measured between Hydrophobic Surfaces due to a Submicroscopic Bridging BubblePhysical Review Letters, 1998