The Cross‐Dehydrogenative Coupling of C-H Bonds: A Versatile Strategy for C-C Bond Formations
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- 8 November 2013
- journal article
- review article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 53 (1), 74-100
- https://doi.org/10.1002/anie.201304268
Abstract
Over the last decade, substantial research has led to the introduction of an impressive number of efficient procedures which allow the selective construction of CC bonds by directly connecting two different CH bonds under oxidative conditions. Common to these methodologies is the generation of the reactive intermediates in situ by activation of both CH bonds. This strategy was introduced by the group of Li as cross-dehydrogenative coupling (CDC) and discloses waste-minimized synthetic alternatives to classic coupling procedures which rely on the use of prefunctionalized starting materials. This Review highlights the recent progress in the field of cross-dehydrogenative C C formations and provides a comprehensive overview on existing procedures and employed methodologies.Keywords
This publication has 317 references indexed in Scilit:
- Direct Selective Oxidative Cross‐Coupling of Simple Alkanes with HeteroarenesAngewandte Chemie-International Edition, 2013
- Direct Selective Oxidative Cross‐Coupling of Simple Alkanes with HeteroarenesAngewandte Chemie, 2013
- Palladium‐Catalyzed Cross‐Coupling: A Historical Contextual Perspective to the 2010 Nobel PrizeAngewandte Chemie-International Edition, 2012
- Palladiumkatalysierte Kreuzkupplungen: eine historische Perspektive im Kontext der Nobel‐Preise 2010Angewandte Chemie, 2012
- Enantioselective Oxidative Cross‐Dehydrogenative Coupling of Tertiary Amines to AldehydesAngewandte Chemie-International Edition, 2012
- Enantioselective Oxidative Cross‐Dehydrogenative Coupling of Tertiary Amines to AldehydesAngewandte Chemie, 2012
- Reactivity and Mechanistic Insight into Visible‐Light‐Induced Aerobic Cross‐Dehydrogenative Coupling Reaction by OrganophotocatalystsChemistry – A European Journal, 2011
- Palladium(II)‐Catalyzed C-H Activation/C-C Cross‐Coupling Reactions: Versatility and PracticalityAngewandte Chemie-International Edition, 2009
- Functionalizing Glycine Derivatives by Direct C-C Bond FormationAngewandte Chemie, 2008
- Moderne Varianten der Mannich-ReaktionAngewandte Chemie, 1998