Application of a Mild Hydrothermal Approach Containing an in Situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)-Containing Fluorides Na4MU6F30 (M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+) Crystal Growth, Structures, and Magnetic Properties
- 4 March 2014
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 136 (10), 3955-3963
- https://doi.org/10.1021/ja412725r
Abstract
A family of rare U(IV)-containing quaternary fluorides, Na4MU6F30 (M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+)), was synthesized in single crystal form via a mild hydrothermal technique utilizing an in situ U(VI) to U(IV) reduction step. The modified hydrothermal route is described, and the conditions to obtain single crystals in high yield are detailed. The crystal structures were determined by single crystal X-ray diffraction. The isostructural fluorides crystallize in a new structure type in the trigonal space group P3̅c1. They exhibit a complex three-dimensional crystal structure consisting of corner- and edge-shared UF9 and MF6 polyhedra. The main building block, a U6F30(6-) group, is arranged to create two distinct hexagonal channels, inside which MF6 octahedra and Na(+) cations are located. The copper-containing member of the series, Na4CuU6F30, is unusual in that the Cu(2+) cation exhibits a rare symmetrical coordination environment consisting of six identical Cu-F bond distances, indicating the lack of the expected Jahn-Teller distortion. Magnetic susceptibility measurements of Na4ZnU6F30 yielded an effective magnetic moment of 3.42 μB for the U(4+) (f(2)) cation in the structure. Measurements of the other members containing magnetic transition-metal cations in addition to U(4+), Na4MU6F30 (M = Mn(2+), Co(2+), Ni(2+), and Cu(2+)) yielded total effective magnetic moments of 10.2, 9.84, 8.87, and 8.52 μB for the Mn-, Co-, Ni-, and Cu-containing materials, respectively. No evidence for long-range magnetic ordering was found down to 2 K. Measurements of the magnetization as a function of applied magnetic field at 2 K for Na4MnU6F30 confirmed that the U(4+) magnetic cation exhibits a nonmagnetic singlet ground state at low temperature. Thermal stability measurements and UV-vis diffuse reflectance spectroscopy are also reported.Keywords
Funding Information
- National Science Foundation (DMR-1149899)
- Office of Basic Energy Sciences (DE-SC0008664)
This publication has 64 references indexed in Scilit:
- Design Study to Increase Plutonium Conversion Ratio of HC-FLWR CoreNuclear Technology, 2012
- Treatment of effluents from uranium oxide productionEnvironmental Technology, 2011
- On the proliferation issues of a fusion fission fuel factory using a molten saltNuclear Engineering and Design, 2010
- UO2/Zry-4 chemical interaction layers for intact and leak PWR fuel rodsJournal of Nuclear Materials, 2010
- Syntheses, Structures, and Characterization of Open-Framework Uranyl GermanatesInorganic Chemistry, 2010
- Thermal reactions of uranium metal, UO2, U3O8, UF4, and UO2F2 with NF3 to produce UF6Journal of Nuclear Materials, 2009
- Uranium and fluorine cycles in the nuclear industryJournal of Fluorine Chemistry, 2009
- Conditions Conducive to Forming Crystalline Uranyl Silicates in High Caustic Nuclear Waste EvaporatorsNuclear Technology, 2006
- A RE-EVALUATION OF THE STRUCTURE OF WEEKSITE, A URANYL SILICATE FRAMEWORK MINERALThe Canadian Mineralogist, 2001
- KNa3(UO2)2(Si4O10)2(H2O)4, a new compound formed during vapor hydration of an actinide-bearing borosilicate waste glassJournal of Nuclear Materials, 2000