Identification of solid-state forms of cucurbit[6]uril for carbon dioxide capture
- 8 January 2013
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 15 (8), 1528-1531
- https://doi.org/10.1039/c3ce27017c
Abstract
Three novel crystalline forms of cucurbit[6]uril (CB[6], 1) have been identified by fine control of the mixing process of a hydrochloride solution of CB[6] with ethanol. The form that exists in nanoplate particles shows permanent porosity upon desolvation and the highest CO2 uptake (15 wt%) at 298 K and 1 bar among any known solid-state forms of CB[6].Keywords
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