Synthetic Control on Structure/Dimensionality and Photophysical Properties of Low Dimensional Organic Lead Bromide Perovskite
- 18 October 2018
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 57 (21), 13443-13452
- https://doi.org/10.1021/acs.inorgchem.8b02042
Abstract
Low dimensional lead halide perovskites have attracted huge research interest due to their structural diversity and remarkable photophysical properties. The ability to controllably change dimensionality/structure of perovskites remains highly challenging. Here, we report synthetic control on structure/dimensionality of ethylenediammonium (ED) lead bromide perovskite from a two dimensionally networked (2DN) sheet to a one dimensionally networked (1DN) chain structure. Intercalation of solvent molecules into the perovskite plays a crucial role in directing the final dimensionality/structure. This change in dimensionality reflects strongly in the observed differences in photophysical properties. Upon UV excitation, the 1DN structure emits white light due to easily formed “self-trapped” excitons. 2DN perovskites show band edge blue emission (∼410 nm). Interestingly, Mn2+ incorporated 2DN perovskites show a highly red-shifted Mn2+ emission peak at ∼670 nm. Such a long wavelength Mn2+ emission peak is unprecedented in the perovskite family. This report highlights the synthetic ability to control the dimensionality/structure of perovskite and consequently its photophysical properties.Funding Information
- Council of Scientific and Industrial Research (MLP030326)
- Department of Science and Technology, Ministry of Science and Technology (EMR/2014/000478, SB/S2/RJN-61/2013)
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