Polyoxometalate-Based Vesicle and Its Honeycomb Architectures on Solid Surfaces
- 12 May 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (22), 8016-8017
- https://doi.org/10.1021/ja042980j
Abstract
The introduction of cationic surfactant DODA as counterions of [Eu(H2O)2SiW11O39]5- can form a mesoscopic supramolecular assembly of (DODA)4H[Eu(H2O)2SiW11O39], which aggregates into vesicles in chloroform. This POM-based vesicle can be further transferred into three-dimensional microporous architectures under moist air. The present methodology shows that, by combining inorganic chemistry and colloidal surface chemistry, a sequential self-assembling approach based on a series of linkable preorganized building blocks allows access to the fabrication of technological applicably POM-based microsized patterns, alternated with the soft lithographic method.This publication has 11 references indexed in Scilit:
- Interaction of sea water and lava during submarine eruptions at mid-ocean ridgesNature, 2003
- Solid-State and Solution Studies of {Lnn(SiW11O39)} Polyoxoanions: An Example of Building Block Condensation Dependent on the Nature of the Rare EarthInorganic Chemistry, 2003
- Polyelectrolyte–surfactant complexes (synthesis, structure and materials aspects)Progress in Polymer Science, 2002
- Three-Dimensionally Ordered Array of Air Bubbles in a Polymer FilmScience, 2001
- Water-Assisted Formation of Micrometer-Size Honeycomb Patterns of PolymersLangmuir, 2000
- Toward Nanodevices: Synthesis and Characterization of the Nanoporous Surfactant-Encapsulated Keplerate (DODA)40(NH4)2[(H2O)n⊂Mo132O372(CH3COO)30(H2O)72]Journal of the American Chemical Society, 2000
- Surfactant-Encapsulated Clusters (SECs): (DODA)20(NH4)[H3Mo57V6(NO)6O183(H2O)18], a Case StudyChemistry – A European Journal, 2000
- Self-organized honeycomb morphology of star-polymer polystyrene filmsNature, 1994
- Synthetic Bilayer Membranes: Molecular Design, Self‐Organization, and ApplicationAngewandte Chemie, 1992
- Lanthanide ion luminescence probes of the structure of biological macromoleculesAccounts of Chemical Research, 1981