Simultaneous In-Line Monitoring of the Conversion and the Coating Thickness in UV-Cured Acrylate Coatings by Near-Infrared Reflection Spectroscopy
- 15 September 2010
- journal article
- research article
- Published by American Chemical Society (ACS) in Analytical Chemistry
- Vol. 82 (19), 8088-8094
- https://doi.org/10.1021/ac100933q
Abstract
Near-infrared (NIR) reflection spectroscopy was used for in-line analysis of the conversion and the coating thickness (5−20 μm) of UV-cured clear and pigmented acrylate coatings. The quantitative evaluation of the recorded spectra was carried out by partial least-squares (PLS) regression, in particular with the PLS2 algorithm, which allows simultaneous prediction of both parameters. The efficiency of this method was investigated in roll coating experiments at line speeds up to 100 m min−1. It was shown that the method is able to compensate for the effect of accidental variations of the coating thickness, which inevitably occur upon changes of the line speed, on the prediction of the conversion. Accordingly, the conversion could be determined with a precision of ±2...3%, whereas the error in the measurement of the thickness was found to be about 0.5−1 μm.Keywords
This publication has 26 references indexed in Scilit:
- Fast and Robust Method for the Determination of Microstructure and Composition in Butadiene, Styrene-Butadiene, and Isoprene Rubber by Near-Infrared SpectroscopyApplied Spectroscopy, 2006
- Combination of NIR, Raman, Ultrasonic and Dielectric Spectroscopy for In‐Line Monitoring of the Extrusion ProcessMacromolecular Symposia, 2005
- Process Analytical TechnologyPublished by Wiley ,2005
- Vibrational Spectroscopic and Ultrasound Analysis for In-Process Characterization of High-Density Polyethylene/Polypropylene Blends during Melt ExtrusionApplied Spectroscopy, 2005
- In-process vibrational spectroscopy and ultrasound measurements in polymer melt extrusionPolymer, 2003
- On the use of recent developments in vibrational spectroscopic instrumentation in an industrial environment: quicker, smaller and more robustVibrational Spectroscopy, 2000
- Near-Infrared Spectroscopy for in situ Cure Monitoring of Dimethacrylate-Based NetworksApplied Spectroscopy, 2000
- Process Analytical Chemistry for SpectroscopistsApplied Spectroscopy, 1998
- Near‐infrared spectroscopy of polymersMakromolekulare Chemie. Macromolecular Symposia, 1991
- Process Analytical ChemistryAnalytical Chemistry, 1987