Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: I. from isolated cluster to 1-D chain

Abstract
The hydrothermal reactions of [A-α-SiW9O34]10−/[A-α-PW9O34]9− with NiCl2·6H2O and amines yielded four unprecedented hybrid high-nuclear Ni-subsituted polyoxotungstates.

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